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GenX Discharge From Chemours Into the Cape Fear River, NC

Analies Dyjak @ Tuesday, February 13, 2018 at 11:47 pm -0500

Analies Dyjak | Policy Analyst

In last weeks blog post, we discussed what a National Pollution Discharge Elimination System (NPDES) permit should look like. This article discusses the major problems with the 2015 Chemours-Fayetteville NPDES permit issued by the North Carolina Department of Environmental Quality

History Of PFAS Discharge By Dupont/Chemours

In 2015, the North Carolina Department of Environmental Quality issued a renewal NPDES permit to the Chemours Dupont manufacturing plant in Fayetteville, North Carolina. Prior to the media spotlight of GenX in the Cape Fear River in the summer of 2017, Chemours (and Dupont) had been receiving permit renewals since the plant was built in the 1970’s. This particular Chemours plant had been illegally discharging PFAS compounds for years. Similar compounds were not listed or identified in the NPDES permit, which immediately raised a red flag. Our team has taken the time to analyze each section of this 2015 NPDES permit renewal.

Problems With The 2015 Chemours Renewal Permit

Units:

First off, there are no units next to the values in the table. The 2015 NPDES permit almost completely lacked uniformity among units. The reader needs to clearly identify if allowable discharge is in mg/kg/day (parts per million), ug/kg/day (parts per billion), and so on. However, Chemours Dupont used “pounds per day” which isn’t constant with the EPA's normal standards of mg/kg/day or ppm. As we discussed in the overview of NPDES permit article, when a permitting agency fails to include units/dosage, they are allowing chemical discharge at any concentration, so long as the total mass does not exceed the stated value. In doing so, they opened up the door for the permit holder to coordinate discharge schedules with their sampling. More on this below.

Sampling:

The second issue is sampling. Chemours mainly used a grab sampling technique to test the surrounding Cape Fear water quality. Grab sampling is a daily one-time collection of water at any given location. This means that Chemours was able to determine the location and time for collecting a sample. As you can probably infer, this would allow Chemours to collect their daily grab sample as far away from the point of discharge as possible. Additionally, this sampling method allows Chemours to collect samples at a time when operation was halted or during a low-discharge period. Either of these sampling tricks could skew concentration levels and water quality being sent to the EPA.

No Plan To Reduce Discharge:

Finally, the National Pollutant Discharge Elimination System was created to help reduce pollution in US waterways. Permitting agencies should include a plan on how they’re working to reduce chemical discharge in their NPDES permit.

Summary

The Chemours NPDES permit is one of many inadequate documents distributed by state governments. Although it’s easy to blame the permitting agency, it’s really the fault of the federal government for not supplying an improved uniform template. Federal and state governments should demand more stringent practices from polluters in terms of allowable limits, uniformity in terms of units, and consistent, thorough, sampling techniques.

Although this particular permit seems is inadequate, there are hundreds of active permits in the US that are much worse. In future articles, we'll be shining some light onto these permits as well.

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Recap of January 25, 2017 H2GO Town Hall Meeting/Expert Panel

Analies Dyjak @ Monday, January 29, 2018 at 8:37 pm -0500

Analies Dyjak, Hydroviv Policy Analyst. 

This past Thursday, January 25th, H2GO and a local news agency hosted an informative meeting to update the public on the GenX crisis that’s unfolding in Brunswick County, North Carolina. The forum consisted of 3 scientists, 2 representatives from the North Carolina Department of Environmental Quality (NCDEQ), local utility providers, and a packed audience of concerned citizens. The mission of the meeting was to communicate to residents any recent actions and discoveries in this public health debacle.

Meeting Topic: Growing Concern About Other PFASs

The public forum made it clear that the scientists and Brunswick County residents are becoming more and more concerned with other perfluroalkyl and polyfluroalkyl subscances (PFASs) that are also present in the Cape Fear River. The scientists concluded that they know even less about these contaminants, which is troubling considering how little is known about GenX.

Our Take: While the presence of other PFASs are new to the nationwide press, they are not new to the scientific community. Dr. Knappe's work has been going on for quite some time, and is highly-respected by the environmental science community (including our science team). It's likely that GenX captured more attention than many other chemicals because it has an ominous (but easy to pronounce) nickname. 

Meeting Topic: Comments From State Regulatory Agencies

A representative from the North Carolina Department of Environmental Quality (NCDEQ) shared the three requests made by the Governor to the Environmental Protection Agency; expedite water quality data on GenX, expedite the risk assessment so that national and state standards could be set, and review the consent order under the Toxic Substance Control Act

Our Take On This: This feels a bit like grandstanding, becasue there are thousands of unregulated contaminants that are currently “in review” by the EPA, and the Clean Water Act only allows a MAXIMUM of 30 unregulated contaminants to be monitored in drinking water every 5 year period. The timescales for progress in these types of things are measured in decades, not months. For reference, chromium 6, whose toxicity and occurrence in US drinking water systems has been established for decades, is still not regulated. This is despite being the fact that it was made famous by the Erin Brockovich Movie (released in 2000). 

What Is Hydroviv Doing To Help Remediate Perfluorinated Compounds (Including GenX) In Drinking Water?

As a company, we're not really in a position to push for long-term regulatory changes, but we have heavily invested in a rapid R&D program to develop an under sink water filtration system that is optimized for GenX removal. Unlike reverse osmosis filters, our system does not require the user to drill a hole in their drain pipe or countertop, so our water filters can be used by homeowners and renters alike. 

Of course, our Water Nerds are also standing by to answer questions about GenX, PFASs, regulatory policy.... even if you have no intention of purchasing one of our filters. Open a chat line on our homepage with one of our Water Nerds or send us an email at hello@hydroviv.com.

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GenX and PFAS Contamination In Drinking Water: What You Need To Know

Analies Dyjak @ Saturday, June 10, 2017 at 3:17 pm -0400
*Updated 1/22/20 to include PFAS map provided by the Environmental Working Group*
 

There has been some major news coverage about "GenX" and other pre GenX perfluoroalkyl/polyfluoroalkyl substances (PFAS) contamination in North Carolina and throughout the entire country. The Environmental Working Group (EWG) just published a list of new PFAS-effected communities, which includes an extensive list of new cities. If you'd like to check out the map, you can find it linked here. Whenever something like this makes it into the news, the facts can quickly become obscured, so the aim of this article is to summarize a few key things to know about GenX and other PFAS in drinking water. If you're curious about water filter that remove PFAS (including GenX) from tap water, check out this Duke/NC State PFAS study. 

What Is GenX?

GenX chemical structure Chemours

GenX is a trade name for a chemical (deduced structure shown above) that went into production around 2010 as an alternative to a perfluorooctanoic acid (also known as PFOA or C8) in the synthesis of PTFE (ie Teflon). PFAS is the broad category in which GenX, PFOA, and PFOS fall under. PFAS are essential for the production of common household products including non-stick pans, firefighting foam, and common outdoor fabrics (e.g. Gore-Tex).

Why Do We Care About GenX And Chemicals Like It?

It's pretty simple: 1) These chemicals are known to be toxic (and this link too) 2) They are persistent in the environment, which means that they don't break down, and can contaminate water far from the contamination source.

Is GenX or Other PFAS Regulated By EPA?

No. Which means that there are no regulatory limits, and municipalities are not required to test for it. There are a lot of chemicals that fall into this category.

Why Is This Such A Big Problem In North Carolina?

A company called Chemours (which was originally spun out of Dupont) produces GenX at a plant in Fayetteville, NC. Discharge from this plant contaminates the Cape Fear watershed.

Are There "Safe" Levels of GenX And Other PFAS In Drinking Water?

Remember, while it's uncomfortable to think about chemicals of any kind existing in drinking water at any concentration, we try and remind people that the dose makes the poison. The example that we like to use is that drinking seawater will kill you from the high salt levels, but putting a pinch of salt in your soup broth is completely fine. The same is true for any chemical. The most credible information that exists at this time on toxicity of PFAS comes from a toxicological profile done by US Center For Disease Control (CDC). In this report, CDC establishes a health advisory level of 20 parts per trillion for the cumulative sum of all PFAS in drinking water, using lifetime exposure levels.

How To Filter GenX And Other PFAS From Drinking Water

If you live in an area that has PFAS levels over the CDC's Health Advisory Levels, you have a few options to remove PFAS. Obviously, as a water filter company, we're partial to our under sink water filtration system and refrigerator and ice maker water filter that were shown to effectively remove GenX in the home of a Wilmington, NC customer under real-world conditions (Reports Can Be Viewed HERE and HERE). These tests were part of an ongoing monitoring program, and we did not pay for the testing. We were also part of a Duke University and NC State study that assessed residential water filters and their ability to remove PFAS from tap water. Hydroviv undersink filters removed PFAS better than major brands such as Brita, Pur, Whirlpool, Berkey, and ZeroWater. The results from this study can be found HERE. These reports reports show that the systems effectively filtered GenX and other PFAS under real-world conditions, for the entire 6 month filter lifetime. Other systems that use reverse osmosis have also been shown to be effective, but they are not without downsides. Our advice to consumers is to demand data collected in real-world conditions (real tap water), not testing in otherwise pure water.

Note: Hydroviv is not affiliated in any way with CFPUA or NC State. In the table below, C4, C5, C6, C7, and C8 all indicate different short and long-chain PFAS variations.

GenX Water Filter

GenX water filter for refrigerator

At Hydroviv, we custom-build water filters using a different approach than reverse osmosis, because of the real-world problems encountered by reverse osmosis users. Instead, our scientists custom-formulate our filter cartridges so they are optimized for each customer's water. There's a lot of proprietary stuff behind what we do, but in the name of transparency we wanted to give more information that we'd normally give about what we are doing to formulate filters for highly soluble compounds like GenX.

1.  We formulate our submicron filter blocks with a blend of activated carbons and elevated levels of a highly porous metal oxide sorbents that other fluoroalkyl compounds have been shown to stick to in the scientific literature. 

2.  We tighten up the pore sizes of our filters, which slows down the flow and increases the amount of time that the water is in contact with the filtration media, so we get much better removal efficiency when compared to granular or powdered media.

Our filters can be ordered through our product pages, and our experts will automatically use your shipping address to know if you are part of the impacted region.

What Are Official Positions On The Situation?

Dupont: In summary, they are saying that even though Chemours is a Dupont spinoff company, they have no comment because it's now a separate entity.

Chemours: Deafening silence.

Municipalities in Southeast North Carolina: "We are in full compliance of Federal Regulations."

Hydroviv: No kidding. You can't be out of compliance if it's not a regulated chemical.

Want More Information About GenX and PFAS In Drinking Water?

We recommend that people take advantage of our "Help no matter what" approach to technical support. Our Water Nerds are happy to discuss our products, or point you to our competitors' products that have also been shown to work. Make sure to chat us on our website or send us an email at hello@hydroviv.com.

*Previously updated November 18, 2017 to include water filter performance data, on May 15, 2018 to include video, and June 22, 2018 to reflect a new toxicological profile that was generated by CDC..*



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EPA Superfund Sites: An Overview on Hazards and the Process

Analies Dyjak @ Monday, August 7, 2017 at 6:00 pm -0400

Emma Schultz, M.S.  |  Scientific Contributor
Updated 12/1/2023 to include latest numbers of Superfund sites by state. 

Do you know where your nearest EPA Superfund Site is? Chances are there is one close by, given that one out of every five Americans lives within three miles of an EPA-designated major hazardous waste site. There are two sites located within four miles of my childhood home, in an idyllic and quiet suburb of St. Paul, Minnesota. I now live within the same distance of five sites -- and I had no clue. 

Superfund Sites - Environmental Hazards

What does it mean to be living so close to so much waste? Common contaminants found at EPA Superfund Sites include asbestos, lead, radiation, and dioxins; these all pose significant risks to human and environmental health. In addition, hazardous substances can leach into the soil from ground level or contaminated water, and can then migrate into nearby homes through subsurface intrusion, entering buildings through foundation cracks and sewer lines. This vapor intrusion then poses further risk to nearby residents, inside of their homes where they would otherwise be inclined to feel safe. Obviously, proximity to a Superfund site is critical; four miles' distance poses a decreased health risk as compared to a mere forty feet.

What Is The Superfund Process?

The concept of EPA Superfund Sites is widely known and understood, but the intricacies of the program and the approach to hazardous waste mitigation are elaborate and prolonged, as can be expected of any federally-funded long-term project.

History: 

In December of 1980, President Jimmy Carter signed into law the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA), now known better as Superfund, which authorized the EPA to remediate hazardous waste spills and sites, and obliged those responsible for the waste - the Potential Responsible Party - to either clean it up on their own dollar or offset the cost of EPA-led cleanup efforts. Superfund had abundant funding early in its existence due to taxes levied on chemicals and oil; those taxes, however, lapsed in 1995, and financing now comes from taxpayers.

Process and Stages:

There are multiple stages in the Superfund process once a site is identified, with the first step being a Preliminary Assessment or Site Inspection. If the site is an emergency such as a chemical spill, Removal Action is taken. Otherwise, Remedial Action is planned for, which often leads to years-long planning, cleanup, and remediation. Community involvement is frequently key during the early stages of Superfund designation, and the Technical Assistance Services for Communities (TASC) program is an outreach effort designed to connect with citizens and businesses for the duration of a Superfund's existence.

After initial study, EPA Superfund Sites are given a score on the Hazard Ranking System. If a site poses enough of a threat to environmental and human health, the EPA announces its addition to the National Priorities List (NPL), pending public comment and input. NPL sites are eligible for extensive, and often long-term, federal funding through the Superfund program. These NPL-listed sites are now officially Superfund sites.

Following NPL designation, a Remedial Investigation and Feasibility Study is conducted. The Remedial Investigation collects information on-site such as water and soil samples, and the follow-up Feasibility Study analyzes various cleanup methods. The EPA then selects the most suitable cleanup alternative and provides it to the community as a Proposed Plan.

A Record of Decision notes the cleanup alternative chosen for the site. In the Remedial Design phase, the cleanup plans are drawn up, and are finally acted upon in the Remedial Action stage. A goal of Remedial Action is to return sites to productive use as quickly as possible. Whether 'productive' means industrial, housing, commercial, or greenspace depends on conversations and input from the surrounding community.

A review of EPA Superfund Site cleanup efforts occurs every five years. If cleanup goals have all been met, a portion or whole of a Superfund site may then be listed for removal from the NPL. In theory, meeting all cleanup goals sounds achievable - especially given the lengthy planning and implementation phases - but there are many sites that remain listed decades later, because groundwater and soil are still polluted.

Where Can You Learn More About Superfund Sites?

Finding out if there are Superfund sites near your home is the first step that all concerned citizens should take. There are 10 Regional Superfund Community Involvement Offices around the country that exist to take your questions and concerns regarding existing or potential Superfund sites. 

Here is the latest list of states and the number of Superfund sites they contain. Be aware that not all toxic contaminants are on the list for contaminated sites to qualify for Superfund. For example, PFAS contaminated sites are not yet regulated under CERCLA. 
States With Superfund Sites

Resources for homeowners:

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Digging Into The Environmental Working Group Tap Water Database

Analies Dyjak @ Saturday, July 29, 2017 at 6:16 pm -0400

Eric Roy, Ph.D.  |  Scientific Founder

This past week, the Environmental Working Group (EWG) released a website where people punch in their zip code, and view contaminants found in their water. As a company that uses water quality data to optimize each customer’s water filter, we applaud EWG for putting in the enormous amount of time & effort to build the database so the public can learn about their water. Unfortunately, we are seeing that these data are being used to generate inflammatory headlines, which can leave consumers confused and unnecessarily panicked.

We will be updating this water quality database blog post as more questions come in. If you have your own question, please reach out to us (hello@hydroviv.com). One of our water nerds will do their best to get back to you very quickly, even if it’s outside of our business hours.

Frequently Asked Questions 

Updated July 31, 2017

Are All Potential Contaminants Listed In The EWG Tap Water Database?

No. The EWG Tap Water Database pulls data from municipal measurements, but municipalities are only required to test for certain things. Simply put, you can’t detect what you don’t look for. One example of this can be seen by punching in Zip Code 28402 (Wilmington, North Carolina) into the EWG Tap Water Database. GenX, a chemical that has been discharged into the Cape Fear River by Chemours since PFOA since 2010, is not listed, even though it’s been in the center of a huge topic of conversation for the past 2 months in the local media.

Why Is The “Health Guideline” Different Than The “Legal Limit?”

The two different thresholds use different criteria. For example, the “Health Guideline” cited by EWG for carcinogens is defined by the California Office of Environmental Health Hazard Assessment (OEHHA) as a one-in-a-million lifetime risk of cancer, while the “Legal Limit” refers to the MCL which is the limit that triggers a violation by EPA. The OEHHA's criteria are established by toxicological techniques, while the EPA limits are negotiated through political channels. We wrote an article that addresses this topic in much more detail for those who are interested.

Why Am I Just Learning About This Now?

The EPA's Safe Drinking Water Act requires municipalities to make water quality test data public in Consumer Confidence Reports. These reports are required to talk about the water's source, information about any regulated contaminants found in the water, health effects of any regulated contaminant found above the regulated limit, and a few other things. As discussed before, the data in the EWG report use different criteria than the EPA, and it's hard for people to make sense of what's what.

Are The Data Correct If My Water Comes From A Private Well?

No. The EWG Tap Water Database only has data for municipal tap water. Private wells are completely unregulated, and there's no requirement to conduct testing. If you'd like us to dig into our additional water quality databases to help you understand likely contaminants in your private well, we're happy to do so. We don't offer testing services, but we're happy to help you find an accredited lab in your area, give advice on which tests to run, and help you interpret the results! We offer this service for free.

What About My City's Water Quality?

Hydroviv makes it our business to help you better understand your water. As always, feel free to take advantage of our “help no matter what” approach to technical support! Our water nerds will work to answer your questions, even if you have no intention of purchasing one of our water filters. Reach out by dropping us an email (hello@hydroviv.com) or through our live chat. You can also find us on Twitter or Facebook!

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