Michelle Scire  |  Scientific Contributor

What Is 1,2,3 Trichloropropane And Where Does It Come From?

1,2,3 Trichloropropane (TCP) is a synthetic chemical that is commonly used as an industrial solvent, cleaning and degreasing agent, and paint and varnish remover.  In California’s Central Valley, widespread TCP contamination was caused by a now-banned fumigant DBCP, which was used to kill nematodes (small worms that live in the soil). When applied to the soil, TCP leaches from the deeper soil to groundwater. When DBCP was banned in 1977 by the EPA, it was commonly used on over 40 crops in California. Unfortunately, TCP is persistent in the environment, and as of November 2017, 395 of the 5863 wells used by public water supplies had levels of TCP that exceeded the California regulatory limit. When looking at a map of contaminated wells (above), you will see a strip right up the center of California from south of Bakersfield to Sacramento with some prominent outliers in Los Angeles, San Diego, Salinas, San Jose, San Francisco, and Chico counties. 

Why Do We Care About TCP?

TCP is some nasty stuff. In the short-term, high levels of inhalation exposure to TCP can cause irritation of eyes, respiratory tract and skin, and has the ability to depress the central nervous system. Moreover, studies in rodents have confirmed it may affect memory, focus and muscle coordination. Long term exposure studies have found exposure in rodents can lead to liver and kidney damage as well as reduced body weight and tumor growth. To get an idea of how toxic TCP is, the 5 part per trillion MCL (legal limit) is equivalent to a single drop of water being diluted into about 5.5 olympic sized swimming pools!.

Timeline of Public Knowledge Related To TCP Toxicity

Data from: HERE

What Took Regulation Of TCP So Long?

While it’d be great if regulatory bodies were able to act quickly, the reality is that regulations take time, often decades to execute. In the case of TCP specifically, Cindy Forbes, the deputy director for Californiawater board’s drinking water program, insists that TCP regulation was a “top priority,” but explained that they had limited resources preventing them from reaching“the finish line.” In California, the process to establish a maximum contaminant level (ie regulatory limit) includes: conducting their own peer-reviewed research, evaluating cost of detection and cleanup, as well as allowing public comment (which undoubtedly includes comments from companies responsible for contamination). Forbes claims, “It’s my priority, it’s the board’s priority,” but one has to wonder what the word priority means when there is scientific research going back 25 years explicitly showing the repercussions of this contaminant. There is only one carcinogen with a lower state public health goal for drinking water, and that is dioxin.

What Can Be Done To Treat Water That Has Been Contaminated With TCP?

Large Scale TCP Remediation Techniques

Because of the contamination primarily leaching into the ground water in California's Central Valley, ground water remediation methods have been established. TCP can be removed with traditional methods such as, “pump and treat granular activated carbon filters (GAC), in-situ oxidation, permeable reactive barriers (zero-valent zinc), dechlorination by hydrogen-releasing compounds, and emerging biodegradation techniques.” A new method was developed recently using, “in-line, pressurized advanced oxidation process (HiPOx) that has the ability to remove TCP from groundwater to below 0.005 μg/L.” The treatment techniquewill depend on the level of contamination in groundwater or soil being treated. While these methods are indeed effective, they are expensive and require long planning/execution periods.

Small Scale (Residential) TCP Removal of TCP

If your home’s water is contaminated with TCP, and large-scale treatment isn’t happening in an acceptable time frame, some residential water filters do remove TCP. Our advice is to find a water filter that is advertised to remove volatile organic compounds (VOCs), and ask the manufacturer for a data sheet that shows effective removal of TCP specifically. 

If you have any more questions about 1,2,3 Trichloropropane contamination, we encourage you to reach out to our “Help No Matter What” technical support through live chat or email (hello@hydroviv.com). Our Water Nerds are happy to answer any questions you may have!

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Emma Schultz, M.S.  |  Scientific Contributor
Updated 12/1/2023 to include latest numbers of Superfund sites by state. 

Do you know where your nearest EPA Superfund Site is? Chances are there is one close by, given that one out of every five Americans lives within three miles of an EPA-designated major hazardous waste site. There are two sites located within four miles of my childhood home, in an idyllic and quiet suburb of St. Paul, Minnesota. I now live within the same distance of five sites -- and I had no clue. 

Superfund Sites - Environmental Hazards

What Is The Superfund Process?

The concept of EPA Superfund Sites is widely known and understood, but the intricacies of the program and the approach to hazardous waste mitigation are elaborate and prolonged, as can be expected of any federally-funded long-term project.

History: 

In December of 1980, President Jimmy Carter signed into law the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA), now known better as Superfund, which authorized the EPA to remediate hazardous waste spills and sites, and obliged those responsible for the waste - the Potential Responsible Party - to either clean it up on their own dollar or offset the cost of EPA-led cleanup efforts. Superfund had abundant funding early in its existence due to taxes levied on chemicals and oil; those taxes, however, lapsed in 1995, and financing now comes from taxpayers.

Process and Stages:

There are multiple stages in the Superfund process once a site is identified, with the first step being a Preliminary Assessment or Site Inspection. If the site is an emergency such as a chemical spill, Removal Action is taken. Otherwise, Remedial Action is planned for, which often leads to years-long planning, cleanup, and remediation. Community involvement is frequently key during the early stages of Superfund designation, and the Technical Assistance Services for Communities (TASC) program is an outreach effort designed to connect with citizens and businesses for the duration of a Superfund's existence.

After initial study, EPA Superfund Sites are given a score on the Hazard Ranking System. If a site poses enough of a threat to environmental and human health, the EPA announces its addition to the National Priorities List (NPL), pending public comment and input. NPL sites are eligible for extensive, and often long-term, federal funding through the Superfund program. These NPL-listed sites are now officially Superfund sites.

Following NPL designation, a Remedial Investigation and Feasibility Study is conducted. The Remedial Investigation collects information on-site such as water and soil samples, and the follow-up Feasibility Study analyzes various cleanup methods. The EPA then selects the most suitable cleanup alternative and provides it to the community as a Proposed Plan.

A Record of Decision notes the cleanup alternative chosen for the site. In the Remedial Design phase, the cleanup plans are drawn up, and are finally acted upon in the Remedial Action stage. A goal of Remedial Action is to return sites to productive use as quickly as possible. Whether 'productive' means industrial, housing, commercial, or greenspace depends on conversations and input from the surrounding community.

A review of EPA Superfund Site cleanup efforts occurs every five years. If cleanup goals have all been met, a portion or whole of a Superfund site may then be listed for removal from the NPL. In theory, meeting all cleanup goals sounds achievable - especially given the lengthy planning and implementation phases - but there are many sites that remain listed decades later, because groundwater and soil are still polluted.

Where Can You Learn More About Superfund Sites?

Finding out if there are Superfund sites near your home is the first step that all concerned citizens should take. There are 10 Regional Superfund Community Involvement Offices around the country that exist to take your questions and concerns regarding existing or potential Superfund sites. 

Here is the latest list of states and the number of Superfund sites they contain. Be aware that not all toxic contaminants are on the list for contaminated sites to qualify for Superfund. For example, PFAS contaminated sites are not yet regulated under CERCLA. 

Resources for homeowners:

Rebecca Labranche | Laboratory Director, A&L Laboratory

How Is Drinking Water Regulated?

The Environmental Protection Agency (EPA) sets regulatory limits for over 90 contaminants in water provided by public water systems. The EPA sets these limits in accordance with the Safe Drinking Water Act to protect public health in the communities that are using this water. The EPA limits are divided into two main categories. National Primary Drinking Water Regulations are legally enforceable standards that apply to public water systems. Primary standards protect public health by limiting the levels of contaminants in drinking water that negatively affect human health. National Secondary Drinking Water Regulations are non-enforceable guidelines regulating contaminants that may cause cosmetic effects (such as skin or tooth discoloration) or aesthetic effects (such as taste, odor, or color) in drinking water. EPA recommends secondary standards for water systems but does not require systems to comply. In addition to the federal EPA standards, The Safe Drinking Water Act (SDWA) gives individual states the opportunity to establish their own drinking water standards if they are not more lenient than those set by the EPA's national standards.

So how do these federal and state regulations affect private well-owners? These same limits and guidelines used for public water are also adopted by most institutions and lenders for home water testing as a way to determine if the property provides potable, safe water. When a home goes up for sale, if the buyer is financing, they will likely be required to test the water. While lenders may be concerned about a potable water source in order to protect their investment, there are no official rules or regulations for determining potability of private wells. Many states and towns do not even require sampling of private wells after installation. It is the responsibility of the homeowner to maintain their well and water supply. 

How Often Should Home Water Testing Be Conducted?

Private well water should be tested a minimum of once per year. Drinking water supplies obtained from shallow dug wells and surface water sources should be tested more frequently as they are more susceptible to contamination. Annual testing of both dug and drilled wells should check for the most common contaminants which are bacteria, nitrates and nitrites. Even if your water has consistently been safe to drink in the past, these parameters could change without you knowing, and affect the safety of your water. New drilled wells should be tested with a more comprehensive water test which includes bacteria, nitrates, nitrites, metals, minerals and radon. This test identifies many common primary and secondary contaminants typically found in the bedrock surrounding the well. This comprehensive test should be repeated every 3 – 5 years to ensure the well is still providing safe water.

What Are The Most Common Types Of Drinking Water Contaminants?

Drinking water contaminants can be divided into several categories: Inorganic Chemicals, Organic Chemicals, Radionuclides and Microorganisms. Testing for every possible analyte would be prohibitively expensive but we have put together a comprehensive test package which covers common problems found in our area.

Laboratories throughout the United States will offer similar packages based on the geology in their area.

What Is The Process For Analyzing Drinking Water?

The process of analyzing drinking water varies by laboratory and their methods used. However, the basic premise is the same for all of them. The first step is to obtain a water test kit from the certified drinking water laboratory that you intend to use for the analysis. Home water testing kits are specific to each laboratory and their methods so it is important not to use another laboratory’s bottles. These test kits come with all the information that is needed to collect the sample and get it back to the laboratory in the required time frame. The sampling instructions are usually step by step and easy to follow. Once the water is received by the laboratory it will be analyzed for the requested parameters and a report will be generated and sent back to the client. The typical turn-a-round time for a comprehensive water test is 2-3 business days.

Using a certified laboratory is very important. They are monitored by their state and undergo periodic inspections to ensure that they are producing the highest quality data. During these inspections their instruments, standard operating procedures, lab technicians, quality control documentation and reporting procedures are reviewed and evaluated. If anything is found to be out of compliance certification for the laboratory can be revoked. In addition to inspections, they also have to complete proficiency tests for each method they conduct to prove that they can perform the method properly and obtain results within the specified limits.

What Are The Risks Associated With Consuming And/Or Using Contaminated Water?

The risks vary greatly depending on which contaminants you have in your water. Common health effects include gastrointestinal illness, reproductive problems, neurological disorders and cancer. These health problems pose a greater threat to young children, pregnant women, the elderly, and people with compromised immune systems. The health effects of drinking contaminated water can range from no physical impact to severe illness or even death.

Some of the effects of drinking contaminated water are known almost immediately. Immediate health related issues generally stem from contamination by pathogens such as total coliform and E.coli. Symptoms include gastrointestinal and stomach illnesses such as nausea, vomiting, cramps, and diarrhea.

Other contaminants pose health effects that may not be observed for many years. Some of the most common ones are:

Arsenic in water occurs naturally as well as from industrial activities. Studies have shown that chronic or repeated ingestion of water with arsenic over a person’s lifetime is associated with increased risk of cancer (of the skin, bladder, lung, kidney, nasal passages, liver or prostate) and non-cancerous effects (diabetes, cardiovascular, immunological and neurological disorders).

Lead can occur due to corrosion of lead containing household plumbing and by industrial pollution. Major toxic effects include anemia, neurological dysfunction/damage and renal impairment.

Uranium is a tasteless, colorless, odorless contaminant. Drinking water with uranium amounts exceeding 30ug/L can lead to increased cancer risk, liver damage, or both.

Copper has both long term and short term effects. Some people with short term exposure, experience gastrointestinal distress, and with long-term exposure may experience liver or kidney damage. It is typically introduced into the water from household plumbing systems.

Fluoride has been shown to reduce tooth decay in children's teeth if they receive an adequate level. The optimal concentration, as recommended by CDC is approximately 1.1 mg/L. In the range of 2.0-4.0 mg/L of fluoride, staining of tooth enamel is possible. Above 4.0 mg/L, studies have shown the possibility of skeletal fluorosis, as well as the staining of teeth.

Radon is the second leading cause of lung cancer. High levels of radon gas occur naturally in Maine soil and water, and can move up into a house from the ground. The house then traps the radon in the air inside. Radon gas can also dissolve into well water, which is then released into the air when you use the water.

What Should I Do If The Laboratory Finds Something In My Water?

If tests on your water indicate problems, the next step is to determine what type of system you need to treat the water. This can be a difficult decision because there is a wide variety of water treatment devices on the market today. Water purifiers range from relatively low-cost, simple filter devices for a kitchen faucet to more expensive, sophisticated systems that treat water from its point of entry into a home. Keep in mind, no one water treatment device can solve every problem.

Rebecca Labranche is the Laboratory Director for A & L Laboratory. A & L Laboratory specializes in drinking water analysis for both public systems and private wells throughout the State of Maine.

Editor's Note: Since this article was first written, more drinking water contaminants have gained attention in the news.These include Per and Polyfluoroalkyl Substances (PFAS), which have recently become Federally regulated in drinking water. If you want to get your water tested and are unsure of what to request, feel free to contact our Water Nerds at hello@hydroviv.com. We can discuss your water concerns and help you prioritize which contaminants to test for.

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Roughly 15 percent of Americans get their tap water from private wells, and this percentage can rise to 40% in rural states like Maine and Vermont. It's no surprise that we receive a lot of questions from people with wells who are are concerned about water quality.

1. Getting A Well “Checked” Is Not The Same As Comprehensive Water Testing

There is a misconception that if someone gets their private well “checked,” it will reveal water quality problems. Unfortunately, that’s not the way it works. A basic water screening has a lot of "blind spots" and gives no information about levels of lead, arsenic, chromium 6, mercury, or VOCs unless you test specifically for those chemicals. Some states have certain testing requirements, but the scope of testing varies from state to state, and most states do not require comprehensive testing. Many banks require that certain water tests be conducted before they will issue a mortgage, but the goal of this testing is often to ensure that there are no faulty systems in the home, not to protect the health of the residents.

Bottom line: The well's owner is responsible for having tests run. Don't assume that the tests that were done as part of the home buying process were comprehensive.

2. Well Water Contamination Often Comes From Natural Sources, Not Humans

Some private well owners are surprised to learn that they have contaminated water, because there are no obvious contamination sources nearby. This is because some contaminants (like arsenic) can occur naturally groundwater at unsafe levels. 

3. Well Water Is Often Corrosive & Can Leach Lead From Plumbing

The lead crisis in Flint put a spotlight on the fact that corrosive water can leach lead from pipes, soldered joints, and plumbing fixtures. Unfortunately, a lot of well owners don't realize that well water can be inherently corrosive, so if a their plumbing predates 2014, (when lead-free standards were fully adopted for home plumbing components) there is potential for lead to leach into the tap water.

4. Contaminant Concentrations (And Recognized Safe Levels) Change With Time

We cannot emphasize enough that people should get their wells tested on a regular basis, because contaminant concentrations and thresholds for “safe” water both change over time.

5. Private Well Owners Are Responsible For Monitoring Their Water Quality, Not EPA

Private wells are not regulated by EPA or State Regulators, so the owners (or prospective owners) are responsible for all well water quality testing. However, figuring out which tests to do and making sense of the results can be confusing. Some states have guidelines and recommendations, but even these can be confusing and contradictory.

Often times, prospective home owners turn to a real estate agent for advice on water quality testing, but we often hear from people who received terrible advice. Most of the time, the mistakes are honest, but there are times when it looks like the agent was trying to facilitate a quick sale.

Ultimately, ensuring water quality of a private well is the individual responsibility of the well’s owner or prospective owner. In support this responsibility, we encourage people to take advantage our Technical Support Team’s “Help At All Costs” policy, and lean on us to provide guidance on which lab to select in your area, which tests to run, and to help interpret the results. This free (no obligation service) can be reached by emailing us (support@hydroviv.com) or by using the live chat function on this page.

We do not have financial agreements or arrangements with water quality test labs, and we do not “over-prescribe” testing.

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